Tanase & Nakajima Group/AboutTakayukiNakajima


なかじま   たかゆき
中島 隆行
准教授
〒630-8285 奈良市北魚屋東町
奈良女子大学理学部化学科
Tel/fax 0742-20-3847
e-mail t.nakajima@cc.nara-wu.ac.jp

昭和45年千葉県佐倉市に生まれる。機能化学大講座准教授。平成19年4月より棚瀬知明教授と協力して有機金属・錯体化学研究グループを運営している。


 


略歴
平成5年3月 早稲田大学理工学部応用化学科卒業(清水功雄研究室)
平成7年3月 早稲田大学理工学研究科修士課程修了(清水功雄研究室)
平成10年3月 早稲田大学理工学研究科博士後期課程修了(清水功雄研究室)
平成7年4月~平成10年3月 日本学術振興会特別研究員 DC1
平成10年4月 理化学研究所基礎科学特別研究員(若槻康雄研究室)
平成14年1月~平成16年3月 エアランゲン・ニュルンベルグ大学(ドイツ)
有機化学科(ザールフランク研究室)アレキサンダーフォンフンボルト奨学生
平成16年4月~平成19年3月 早稲田大学理工学術院応用化学科 助手(清水功雄研究室)
平成19年4月 奈良女子大学理学部化学科 准教授(棚瀬、中島研究室)

専門分野
有機金属化学、錯体化学、超分子化学

学会
日本化学会、有機合成化学協会、近畿化学協会


業績リスト

(1)T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. Shimizu, Y. Yamamoto, Y. Wakatsuki,
Preparation and Structure of the First Ansa-Molybdenocene and Tungstenocene Derivatives. Reaction of [O(SiMe2C5H4)2]MoH2 with Methyl Methacrylate to Prove the Olefin Attacking Site
J. Organomet. Chem. 473, 155-162 (1994).
(2) T. Nakajima, T. Mise, I. Shimizu, Y. Wakatsuki,
“A Photochemical Route to Heterometallic Complexes. Synthesis and Structural Characterization of Di- and Trinuclear Complexes Having a Molybdenocene or Tungstenocene Unit”
Organometallics 14, 5598-5604 (1995).
(3) H. Koshino, T. Nakajima, Y. Wakatsuki, K. Kobayashi, J. Uzawa,
“1H-31P Pulsed Field Gradient Heteronuclear Multiple-Bond Correlation (PFG-HMBC) Spectroscopy”
RIKEN Review 12, 37-38 (1996).
(4) I. Shimizu, M. Fujita, T. Nakajima, T. Satoh,
“Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins”
Synlett 887-890 (1997).
(5) I. Shimizu, K. M. Khien, M. Nagatomo, T. Nakajima, A. Yamamoto,
“Molybdenum-Catalyzed Aromatic Substitution with Olefins and Alcohols”
Chem. Lett. 26, 851-852 (1997).
(6) T. Nakajima, I. Shimizu, K. Kobayashi, H. Koshino, Y. Wakatsuki
“Facile P-C Bond Cleavage of Trimethylphosphine at a Heterodimetallic (Ni-W) Center”
Inorg. Chem. 36, 6440-6442 (1997).
(7) T. Nakajima, I. Shimizu, K. Kobayashi, Y. Wakatsuki
“Synthesis of Triangular and Tetrahedral Heteronuclear Metal Clusters Using Hydride Complexes of Cyclopentadienylrhodium and -ruthenium as the Precursors”
Organometallics 17, 262-269 (1998).
(8) T. Nakajima, A. Ishiguro, Y. Wakatsuki
“Synthesis of Mixed-Metal High-Nuclearity Clusters by Fusion of Anionic Ruthenium Carbido Clusters through Palladium Units”
Angew. Chem. Int. Ed. 39, 1131-1134 (2000).
(9) T. Nakajima, A. Ishiguro, Y. Liu, T. Chihara, Y. Wakatsuki
“High-Nuclearity Cluster Complexes and Their Reaction with Air-Polluting SO2 Gas Molecules”
RIKEN Review, 42, 45-48 (2001).
(10) T. Nakajima, A. Ishiguro, Y. Wakatsuki
“Formation of Super Wires of Clusters by Self-Assembly of Transition Metal Cluster Anions with Metal Cations”
Angew. Chem. Int. Ed. 40, 1066-1068 (2001). (Selected as VIPs)
(11) A. Ishiguro, Y. Liu, T. Nakajima, Y. Wakatsuki
“Efficient Reduction of Sulfur Dioxide with Hydrogen over TiO2-Supported Catalysts Derived from Ruthenium Salts and Ruthenium Cluster Complexes”
J. Catal. 206, 159-164 (2002).
(12) Ishiguro, T. Nakajima, T. Iwata, M. Fujita, T. Minato, F. Kiyotaki, Y. Izumi, K. Aika, M. Uchida, K. Kimoto, Y. Matsui, Y. Wakatsuki
“Nanoparticles of Amorphous Ruthenium Sulfide Easily Obtainable from a TiO2-Supported Hexanuclear Cluster Complex [Ru6C(CO)16]2-: A Highly Active Catalyst for the Reduction of SO2 with H2”
Chem. Eur. J. 8, 3260-3268, (2002).
(13) Y. Izumi, T. Minato, K. Aika, A. Ishiguro, T. Nakajima, Y. Wakatsuki
“Supported Ruthenium Carbido-Cluster Catalysts for the Catalytic Removal of Nitrogen Monoxide and Sulfur Dioxide: the Preparation Process Monitored by Sulfur K-Edge X-ray Absorption Near-Edge Structure”
Studies in Surface Science and Catalysis 143 (Scientific Bases for the preparation of Heterogeneous Catalysts), 361-368 (2002).
(14) T. Minato, Y. Izumi. K. Aika, A. Ishiguro, T. Nakajima, Y. Wakatsuki
“Nitric Oxide Reduction by Carbon Monoxide over Supported Hexaruthenium Cluster Catalysts. 1. The Active Site Structure That Depends on Supporting Metal Oxide and Catalytic Reaction Conditions”
J. Phys. Chem. B 107, 9022-9028 (2003).
(15) R. W. Saalfrank, I. Bernt, F. Hampel, A. Scheurer, T. Nakajima, S. H. Z. Huma, F. W. Heinemann, M. Schmidtmann, A. Müller
“Self-Assembly and Crystal Structure of a Novel Hetero-Octametallic Molecular Box”
Polyhedron 22, 2985-2989 (2003).
(16) R. W. Saalfrank, C. Deutscher, H. Maid, A. M. Ako, S. Sperner, T. Nakajima, W. Bauer, F. Hampel, B. A. Heβ, N. J. R. van Eikema Hommes, R. Puchta, F. W. Heinemann
“Synthesis, Structure, and Dynamics of Six-Membered Metallacoronands and Metallodendrimers of Iron and Indium”
Chem. Eur. J. 10, 1899-1905 (2004).
(17) R. W. Saalfrank, C. Deutscher, S. Sperner, T. Nakajima, A. M. Ako, E. Uller, F. Hampel, F. W. Heinemann
“Six-Membered Metalla-Coronands. Synthesis and Crystal Packing: Columns, Compartments, and 3D-Networks”
Inorg. Chem. 43, 4372-4382 (2004).
(18) R. W. Saalfrank, T. Nakajima, N. Mooren, A. Scheurer, H. Maid, F. Hampel, C. Trieflinger, J. Daub
“Syntheses and Properties of Metal-Centered Mixed-Valent [NEt4]{MnIIÌ[MnII3MnIII3Cl6L6]} Manganese Wheels”
Eur. J. Inorg. Chem. 1149-1153 (2005).
(19) T. Igarashi, T. Inada, T. Sekioka, T. Nakajima, I. Shimizu
“One-Pot Synthesis of Substituted Quinolines by Iridium-Catalyzed Three-Component Coupling Reaction”
Chem. Lett. 34, 106-107 (2005).
(20) T. Inada, T. Nakajima, I. Shimizu
“One-Step Synthesis of Ethyl Quinaldates by Lewis Acid Catalyzed Three-Component Coupling Reaction of Aromatic Amines, Aliphatic Aldehydes and Ethyl Glyoxylate”
Heterocycles 66, 611-619 (2005).
(21) S. Sueki, T. Igarashi, T. Nakajima, I. Shimizu
“Synthesis of b-amino Ketones by Iridium(III)-Catalyzed Direct-Mannich Reaction”
Chem. Lett. 35, 682-683 (2006).
(22) T. Nakajima, T. Inada, I. Shimizu
“Short Step Synthesis of Natural 2-Arylquinolones Based on Iridium-Catalyzed Three-Component Coupling Quinoline Synthesis”
Heterocycles 69, 497-504 (2006).
(23) T. Nakajima, T. Inada, T. Igarashi, T. Sekioka, I. Shimizu
“Facile Three-Component Synthesis of Substituted Quinolines Catalyzed by Iridium(III) Complex”
Bull. Chem. Soc. Jpn. 79, 1941-1949 (2006).
(24) R.W. Saalfrank. A. Scheurer, R. Prakash, F. Hampel, T. Nakajima, F. W. Heinemann, R. Leppin, B. Pilawa, H. Rupp, P. Muller
“Synthesis, Redox and Magnetic Properties of a Neutral, Mixed-Valent Heptanuclear Manganese Wheel with S =27/2 High-Spin Ground State”
Inorg. Chem. 46, 1586-1592 (2007).
(25) T. Nakajima, K. Nakayama, I. Shimizu
“Synthesis of Isotope-labelled [1-13C]-amino Acids from 13CO2”
J. Label. Compd. Radiopharm. 50, 622-623 (2007).
(26) T. Nakajima, H. Konomoto, H. Ogawa, Y. Wakatsuki
“Reactivities Governed by a single Metal atom M in the Mixed-metal High-nuclearity Clusters having [Ru5M(C)] core (M = Co, Rh, Pd): Site-nonselective, Site-selective, and Chemo-selective variations in the SO2-trapping Reactions”
J. Organomet. Chem. 692, 4886-4894 (2007).
(27) T. Nakajima, H. Konomoto, H. Ogawa, Y. Wakatsuki
“Synthesis of Three-component High Nuclearity Cluster Complexes with Ruthenium Carbido Carbonyl Clusters as a Building Block”
J. Organomet. Chem. 692, 5071-5080 (2007).
(28) R. Ogawa, Y. Shigemori, K. Uehara, J. Sano, T. Nakajima, I. Shimizu
“Enantioselective Elimination of Pd-H from h3-Allylpalladium-TolBINAP Complexes. Evidence of Syn Elimination Pathway”
Chem. Lett. 36, 1338-1339 (2007).
(29) R. Ogawa, T. Nakajima, I. Shimizu
“Phosphine-dependent Stereoselective Nucleophilic Reaction to Bicyclic Bis-m-dichloro- h3-Allylpalladium Complexes”
Chem. Lett. 37, 278-279 (2008).
(30) Y. Takemura, T. Nakajima, T. Tanase, M. Usuki, H. Takenaka, E. Goto and M. Mikuriya
“Dynamic Structural Changes of Pentacopper(II) Chains Supported by N6-Donor Ligands”
Chem. Commun. 1664-1666 (2009).
(31) Y. Takemura, H. Takenaka, T. Nakajima, and T. Tanase
“Hexa- and Octagold Chains from Flexible Tetragold Molecular Units Supported by Linear Tetraphosphine Ligands”
Angew. Chem. Int. Ed. 48, 2157-2161 (2009).
(32) Y. Takemura, T. Nakajima, and T. Tanase
“Synthesis and Characterization of Linear Tetranuclear Silver(I) Complexes Bridged by Tetraphosphine Ligands”
Eur. J. Inorg. Chem. 4820-4829 (2009).
(33) Y. Takemura, T. Nakajima, T. Tanase
“Interconversion between ladder-type octanuclear and linear tetranuclear copper(I) complexes supported by tetraphosphine ligands”
Dalton Trans. 10231-10243 (2009).
(34) Y. Takemura, Y. Okui, B. Kure, T. Nakajima, T. Tanase, M. Mikuriya, M. Takahashi
“Octanuclear Iron(I) Complexes Supported by Kemp’s Tricarboxylate Ligands”
Inorg. Chim. Acta. 379 100-108 (2011).
(35) A. Hosokawa, B. Kure, T. Nakajima, K. Nakamae, T. Tanase
“Intermolecular Metal-Metal Bond Rearrangement in a Pt2PdHg Heterometallic Cluster Forming a HgI-PdI Covalent Bond”
Organometallics 30, 6063-6066 (2011).
(36) Y. Okui, F. A. Catusanu, R. Kubota, B. Kure, T. Nakajima, T. Tanase, T. Kajiwara, M. Mikuriya, H. Miyasaka, M. Yamashita
“Systematic Expansion of Supercubane Cores in Manganese Oxo Clusters with Tricarboxylate Ligands”
Eur. J. Inorg. Chem. 4325-4330 (2011).
(37) Y. Takemura, T. Nishida, B. Kure, T. Nakajima, M. Iida, and T. Tanase
“Stepwise Construction of Au4Ag4Cu2 Coinage Rings Supported by Linear Tetraphosphine Ligands”
Chem. Eur. J. 17, 10528-10532 (2011). (Inside Cover Picture)
(38) A. Yoshii, H. Takenaka, H. Nagata, S. Noda, K. Nakamae, B. Kure, T. Nakajima, T. Tanase
“Heterotrinuclear Complexes with Pd, Rh, and Ir Ions Assembled by Conformational Switch of a Tetraphosphine Ligand around Pd Center”
Organometallics 31, 133-143 (2012).
(39) T. Nakajima, S. Kurai, S. Noda, M. Zouda, B. Kure, T. Tanase
”Cyclic Trinuclear Rh2M Complexes (M = Rh, Pt, Pd, Ni) Supported by meso-1,3-bis[(diphenylphosphinomethyl)phenylphosphino]propane”
Organometallics 31, 4283-4294 (2012).
(40) B. Kure, A. Taniguchi, T. Nakajima, T. Tanase
“Hydride-Bridged NiRh Complexes with Tunable N3S2 Dithiolato Ligands and Their Utilization as Catalysts for Hydrogenation of Aldehydes and CO2 in Aqueous Media”
Organometallics, 31, 4791-4800 (2012).
(41) E. Goto, R. Begum, A. Hosokawa, C. Yamamoto, B. Kure, T. Nakajima, T. Tanase
“Hybride-bridged Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Derived from Reductive Coupling of Pt2M Building Blocks Supported by Triphosphine Ligands”
Organometallics, 31, 8482-8497 (2012).
(42) T. Nakajima, K. Seto, F. Horikawa, I. Shimizu, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, and M. Mikuriya
“Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands”
Inorg. Chem. 51, 12503-12510 (2012).
(43) B. Kure, T. Nakajima, T. Tanase
“Synthesis and structure of a dinuclear NiIIIrIII hydride complex supported by a N3S2 bridging ligand: Comparison of property and reactivity of dinuclear NiII(m-H)MIII units (M = Rh, Ir) in aqueous media”
J. Organomet. Chem. 733, 28-35 (2013).
(44) T. Nakajima, M. Sakamoto, S. Kurai, B. Kure, T. Tanase
“Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centres”
Chem. Comm. 49, 5239-5338 (2013). (Front Cover Picture)
(45) T. Tanase, S. Hatada, A. Mochizuki, K. Nakamae, B. Kure, T. Nakajima
“Flexible, Linear, Tetranuclear Palladium Complexes Supported by Tetraphosphine Ligands with Electron-withdrawing Groups”
Dalton Trans. 42, 15941-15952 (2013). (Inside Cover Picture)
(46) T. Nakajima, Y. Fukushima, M. Tsuji, N. Hamada, B. Kure, T. Tanase
“Configurational Isomerization of Dinuclear Iridium and Rhodium Complexes with a Series of NPPN Ligands, 2-PyCH2(Ph)P(CH2)nP(Ph)CH2-2-Py (Py = pyridyl, n = 2-4)”
Organometallics 32, 7470-7477 (2013).
(47) T. Tanase, R. Otaki, T. Nishida, H. Takenaka, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, T. Tsubomura
“Strongly Luminous Tetranuclear Gold(I) Complexes Supported by Tetraphosphine Ligands, meso- or rac-Bis[(diphenylphosphinomethyl)phenylphosphino]methane”
Chem. Eur. J. 20, 1577-1596 (2014).
(48) E. Goto, R. A. Begum, C. Ueno, A. Hosokawa, C. Yamamoto, K. Nakamae, B. Kure, T. Nakajima, T. Kajiwara, T. Tanase
“Electron-Deficient Pt
2M2Pt2 hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands”
Organometallics 33, 1893-1904 (2014). (Back Cover Picture)
(49) T. Tanase, C. Yamamoto, B. Kure, T. Nakajima
“One-Dimentional Anisotropic Metal-Organic Module Containing Pt6 Chain Terminated with Redox Active Ferrocenyl Units”
Chem. Lett. 43, 913-915 (2014).
(50) B. Kure, M. Sano, T. Nakajima, T. Tanase
“Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers that Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H2meppp = meso -1,3-Bis[(mercaptoethyl)phenylphosphino]propane)”
Organometallics 33, 3950-3965 (2014).
(51) T. Nakajima, M. Tsuji, N. Hamada, Y. Fukushima, B. Kure, T. Tanase
“Synthesis and Structures of Pd2M2 (M = Cu, Au) and Pd2M (M = Cu, Ag) Mixed-metal Complexes Supported by NPPN Tetradentate Ligands”
J. Organomet. Chem. 768, 61-67 (2014).
(52) T. Nakajima, K. Seto, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, H. Sakiyama
“Tetranuclear Nickel and Cobalt Complexes with an Incomplete Double-Cubane Structure - Homo- and Heterometallic Complexes and Their 1D Coordination Polymers”
Eur. J. Inorg. Chem. 5021-5033 (2014).

(53) K. Nakamae, B. Kure, T. Nakajima, U. Ura, T. Tanase
“Facile Insertion of Carbon Dioxide into Cu2(m-H) Dinuclear Units Supported by Tetraphosphine Ligands”
Chem. Asian J. 9, 3106-3110 (2014). (Cover Picture)
(54) K. Nakamae, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, T. Tanase
“Self-Alignment of Low-Valent Octanuclear Palladium Atoms”
Angew. Chem. Int. Ed. 54, 1016-1021 (2015).
(55) A. Scheurer, J. Korzekwa, T. Nakajima, F. Hampel, A. Buling, C. Derks, M. Neumann, L. Joly, K. Petukhov, K. Gieb, P. Müller, K. Kuepper, and K. Meyer
“Synthesis, Magnetic Properties, and X-ray Spectroscopy of Divalent Cobalt(II) and Nickel(II) Cubanes [MII4(HL2)4(OAc)4]”
Eur. J. Inorg. Chem. 1892-1901 (2015).
(56) T. Tanase, S. Hatada, S. Noda, H. Takenaka, K. Nakamae, B. Kure, T. Nakajima
“Stepwise Expansion of Pd Chains from Binuclear Palladium (I) Complexes Supported by Tetraphosphine Ligands”
Inorg. Chem. 54, 8298-8309 (2015).
(57) T. Tanase, A. Yoshii, R. Otaki, K. Nakamae, Y. Mikita, B. Kure, T. Nakajima
“Synthesis and structures of dinuclear RhIII and IrIII complexes supported by a tetraphosphine, meso-or rac-bis{[(diphenylphosphinomethyl)phenyl]phosphino]}methane”
J. Organomet. Chem. 797, 37-45 (2015).
(58) T. Tanase, M. Chikanishi, K. Morita, K. Nakamae, B. Kure, T. Nakajima
“Gold and Silver Chains Supported by Linear Hexaphosphine Ligands”
Chem. Asian J. 10, 2619-2623 (2015).
(59) T. Nakajima, S. Noda, M. Sakamoto, A. Matsui, K. Nakamae, B. Kure, Y. Ura and T. Tanase
“Oxidative Addition of Aromatic ortho C‒H Bond of Tetraphosphine to Asymmetric Diiridium(I) Centres”
Dalton Trans. 45, 4747-4761 (2016).
(60) T. Tanase, K. Koike, M. Uegaki, S. Hatada, K. Nakamae, B. Kure, Y. Ura, T. Nakajima
“Electron-rich Linear Triplatinum Complexes Stabilized by a Spinning Tetraphosphine, tris(diphenylphosphinomethyl)phosphine”
Dalton Trans. 45, 7209-7214 (2016).
(61) 7. T. Tanase, K. Yamamoto, B. Kure,T. Nakajima
“Synthesis and Structure of Trihydride Hexaplatinum Complex Supported by Triphosphine Ligands, [Pt6(H)(H)2(dpmp)4]BH4 (dpmp = bis(diphenylphosphinomethyl)phenylphosphine)”
J. Organomet. Chem. 814, 35-41 (2016).
(62) T. Nakajima, C. Yamashiro, M. Taya, B. Kure, T. Tanase
“Systematic Synthesis of Di-, Tri-, and Tetranuclear Homo- and Heterometal Complexes Using a Mononuclear Copper Synthon with a Tetradentate Aminoalcohol Ligand”
Eur. J. Inorg. Chem. 2764-2773 (2016).
(63) T. Nakajima, Y. Kawasaki, B. Kure, T. Tanase
“Homo- and Heterodinuclear Rh and Ir Complexes Supported by SNn Mixed-donor Ligands (n = 2─4). Stereochemistry and Coordination-Site-Exchange Reactions of Cp*M (M = Rh, Ir) Units”
Eur. J. Inorg. Chem. 4701-4710 (2016).
(64) T. Tanase, K. Morita, R. Otaki, K. Yamamoto, Y. Kaneko, K. Nakamae, B. Kure, T. Nakajima
“Chiral Self-Recognition between Stereogenic Tetrapalladium Units Affording Pd8 Chains Supported by Homochiral Tetraphosphines”
Chem. Eur. J. 23, 524-528 (2017). (Back Cover Picture)
(65) T. Tanase, K. Yamamoto, R. Hatano, K. Nakamae, B. Kure, Y. Ura, T. Nakajima
“Linear Triplatinum Tetrahydride Complex Supported by Triphosphine Ligands, [Pt3(µ-H)2(H)2(µ-dpmp)2](BF4)2 {dpmp = bis(diphenylphosphinomethyl)phenylphosphine}”
Eur. J. Inorg. Chem. 1422-1426 (2017). (Front Cover Picture)
(66) K. Nakamae, M. Tanaka, B. Kure, T. Nakajima, Y. Ura, T. Tanase
“A Fluxional Cu8H6 Cluster Supported by Bis(diphenylphosphino)methane and Its Facile Reaction with CO2 “
Chem. Eur. J. 23, 9457-9461 (2017). (Inside Cover Picture)
(67) B. Kure, M. Sano, N. Watanabe, T. Nakajima, T. Tanase
“Synthesis and Reactivity of Thiolate-Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S-Bidentate NiP2S2 Metalloligands“
Eur. J. Inorg. Chem. 4097-4109 (2017). (Front Cover Picture)
(68) T. Nakajima, Y. Kamiryo, K. Hachiken, K. Nakamae, Y. Ura, T. Tanase
“Tri- and Tetranuclear Copper Hydride Complexes Supported by Tetradentate Phosphine Ligands”
Inorg. Chem. 57, 11005-11018 (2018).


著書
中島隆行 若槻康雄 共著 第5版実験化学講座21有機遷移金属化合物、超分子錯体、2004年、丸善 (11章2節:有機金属クラスター錯体の執筆担当)


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